While former "Friends" actress, Jennifer Aniston is allegedly busy “wrecking” homes, her ex-husband’s partner who left her for Angelina Jolie, has continued to build strong ones - - through her charity works.

The Mr. & Mrs. Smith star is the latest face for Luis Vuitton and her first project involves promoting the “Core Values” campaign.

The Sydney Morning Herald is reporting that Jolie donated part of her pay cheque to charity works. This should not come as a surprise however, for the ad was shot in Cambodia, the native home of her eldest and first adopted son, Maddox.

A photo by famed photographer, Annie Leibovitz, for the LV’s Core Values- campaign, captured The Tourist star sitting casually in a boat, sporting a natural look, wearing no make-up and barefooted, and only her own personal Louis Vuitton bag slung in her shoulder.

"People are not used to seeing Angelina in this situation," the vice president for Louis Vuitton, Pietro Beccari was quoted as telling Women's Wear Daily by The Sydney Morning Herald

The whole concept is developed for Angie and images of Jolie's fresh face stormed the web.

"I like the fact that it's a real moment. This travel message we give through personal journeys is a fundamental one for the brand... This campaign is about a very special person and a very special journey," said the LV official.

Angie joins other prominent personalities who have represented Luis Vuitton for various campaigns including, U2 frontman Bono and Sir Sean Connery.

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